RCAAP Repository

Abstract In Brazil, malacoculture is developed mainly in the state of Santa Catarina, followed by São Paulo and Rio de Janeiro. In the course of the development of Brazilian mariculture, legislation has addressed the sanitary requirements necessary for bivalve commercialization. However, monitoring phycotoxins is a challenge, due to often costly reference methods. In this context, this study evaluated the use of alternative ecotoxicological and bioanalytical methods using Artemia franciscana (brine shrimp) lethality assessments. The results confirm that, although correlations between the reference mouse assay and the brine shrimp assays were not high, the alternative brine shrimp assay may be incorporated into phycotoxin monitoring programs, as hepatopancreas methanolic extracts of mussel (Perna perna) containing DSP resulted in high lethality rates. Therefore, further methodological adjustment studies and the inclusion of other enzymatic and toxicological models are required to further assess these differences, and associations between ecotoxicological methods as early-alarm methods are encouraged.

Abstract Among the waste produced daily by communities are those resulting from the treatment of water for public supply, with local specificities that reflect the characteristics and uses of the land. Despite the continuous generation and inadequate disposal still current in Brazil, there is little information on these residues. The data related to the composition of these sludges are essential for the study of alternatives for beneficial uses and for determining the risks to the environment and human health from inadequate disposal. It is in this context that the present study was developed, with the objective of identifying the physical-chemical characteristics of sludge produced in water treatment plants (WTPs) and of verifying the presence of these elements in the waters of the source used for supply. Such research was carried out through a case study in two WTPs in the state of São Paulo that perform surface abstraction. Therefore, in each of the WTPs, samples of densified sludge, representative of the dry and rainy periods, were characterized. The chemical findings of the sludge have been compared to the historical series of a decade of monitoring of the water quality of the sources of these WTPs. Among the main results, concentrations above the reference limits for the inert residues of aluminum, iron, manganese and barium in sludge are highlighted, as well as the existence of iron and manganese in the raw water collected and the variations in the concentrations of iron, sodium and manganese in the sludge due to the climatic conditions.

Abstract The goal of this study was to assess the temporal dynamics of an accumulation reservoir in an accessible and accurate way. The study was conducted on the Serra da Mesa Dam (GO) using orbital images. To estimate the flat area of the dam surface, Landsat TM and OLI images for the period 1998 to 2018 were used. The images were processed using the Google Earth Engine platform (GEE) in order to obtain the dam surface area (km²) and relate it to the flow, altimetric height and volume of the reservoir over the years. The dam showed constant variation of water since its inception, with a decreasing trend. The highest values of the reservoir measurement metrics were observed in the years coincident with the largest areas of the dam, and inversely proportional to the years of the appearance of new dams upstream. More than 90% of the altimetric height variation of water could be explained by the flat area of the dam. The processing platform using the GEE is effective to provide extensive temporal analysis using a large volume of data in a short time, with accurate and robust results.

Abstract Water-quality monitoring is one of the main instruments for water-resource management. This work therefore evaluated the water quality of the contribution basin of the Sinnott water treatment plant as well as the relationship between physicochemical water parameters, and analyzed the seasonal variation of water quality parameters as a function of rainfall. The study area encompassed the contribution basin of the Sinnott water treatment plant, formed mainly by the drainage areas of the Pelotas stream and its tributary, the Quilombo Stream, located in the city of Pelotas - Rio Grande do Sul, Brazil. A set of 118,368 data points for each stream was analyzed between 2007 and 2012. The following water quality parameters were evaluated: turbidity, temperature, color, pH, hardness, dissolved oxygen, organic matter, and alkalinity. Results showed that dissolved oxygen and water pH values conformed with Brazilian legislation in the 6 years evaluated. However, water color was the parameter that remained the greatest number of days above the set limits, mainly in the Pelotas Stream. Result indicates the need for conservation actions in the catchment, especially considering the importance of color for the assessment of water quality for public supply, in terms of both treatment costs and of public health. Highest values for water color, turbidity, and organic matter coincided with the occurrence of the highest rainfall values. Agricultural activities may potentiate sedimentation in the contribution basin of the Sinnott water treatment plant.

Abstract The phytosorption potential of metals of Hydrocotyle ranunculoides was evaluated for the mitigation of water pollution in the high Andean wetlands of Peru. The plants were selected from 10 wetland sites in the community of Pomachaca- Tarma and were washed with potable water, dried, ground, weighed, chemically digested and read with Varian AA 240 atomic absorption equipment. The plant showed copper concentrations in the root (12.08 ± 1.67 mg/kg) greater than the stem (7.37 ± 1.00 mg/kg), followed by the leaves (7.37 ± 1.56 mg/kg). Lead concentration in the root was 0.228 ± 0.711 mg/kg, but was not found in the stem or leaves. The highest zinc concentration was in the root (67.52 ± 12.57 mg/kg) to the stem (53.30 ± 0.61 mg/kg), followed by the leaves (43.99 ± 8.49 mg/kg). Finally, iron was higher in the root (5571.28 ± 693.94 mg/kg) than in the leaves (342.76 ±122.09 mg/kg), followed by the stem (291.94 ± 54.84 mg/kg). Surrounding water had pH between 7.2 and 7.6; no copper and lead were found, zinc was 0.005 ± 0.012 mg/L and iron was 0.009± 0.007 mg/L. In the sediment, copper was 26.12 ± 0.65 mg/kg, lead 28.25 ± 2.41 mg/kg, zinc 85.98 ± 11.38 mg/kg and iron 26111.89 ± 614.37 mg/kg. These results indicate that this plant absorbs metals in the order of Fe>Zn>Cu>Pb and is an alternative for the development of phytotechnology, oriented to the treatment of effluents with metals that contaminate water in wetlands.

Abstract Population growth and the need to exploit natural resources to produce food and guarantee food sovereignty reduce water availability, which can influence nutrient absorption capacity and production of plants. This study evaluated whether variations in soil water replacement levels promote changes in the mineral composition and biomass productivity of forage cactus varieties. A field experiment was conducted in a randomized block design with five levels of reference evapotranspiration replacement (25, 50, 75, 100 and 125% ETo) and three replicates. Contents of the macronutrients N, P, K, Ca, Mg and S; micronutrients Cu, Fe, Mn, Zn, Cl, Na and B; and biomass productivity were quantified in two varieties of forage cactus (‘Orelha de Elefante Mexicana’ and ‘Miúda’). The data were subjected to principal component and multivariate variance analysis. The mineral composition of the forage cactus varieties ‘Miúda’ and ‘Orelha de Elefante Mexicana’ can be optimized from soil water management, so as to obtain adequate nutritional balance for higher yield. The replacement level of 75% ETo promoted greater balance between nutrients in the cladodes of the forage cactus variety ‘Miúda’, while ‘Orelha de Elefante Mexicana’ had better nutritional balance with the replacement levels of 100 and 125% ETo. Soil water replacement levels of 100 and 125% ETo promote high accumulation of Na+ and Cl- ions in the cladodes of the forage cactus varieties studied. Highest biomass productivity of the varieties ‘Orelha de Elefante Mexicana’ and ‘Miúda’ was obtained with 75 and 100% ETo replacement levels, respectively. Among the varieties, ‘Orelha de Elefante Mexicana’ had a higher capacity for nutrient accumulation and biomass productivity, followed by ‘Miúda’, under the edaphoclimatic conditions of the Brazilian semiarid region.

Abstract Phosphorus (P) is an essential element for vineyard productivity. This study assessed the influence of parent material on organic P fractions in vineyard soils of basaltic and rhyodacitic origin. The experiment was conducted in four municipalities located in mountainous regions in Santa Catarina, Brazil: Urubici, São Joaquim, Campos Novos, and Água Doce. Disturbed soil samples were collected between grapevine rows at depths of 0.00-0.05, 0.05-0.10, 0.10-0.20, and 0.20-0.40 m. Soil chemical attributes (pH in H2O, Ca2+, Mg2+, Al3+, P, K+, and H + Al), total organic carbon (TOC), available and residual P, labile P (extracted with sodium bicarbonate), moderately labile P (extracted with sulfuric acid), and moderately resistant P (extracted with sodium hydroxide) were determined. Soil parent material influenced the dynamics of phosphorus in vineyard soils. Both P forms (available and solution equilibrium P) and P organic fractions (labile, moderately labile, and moderately resistant P), are affected by the parent material. Basaltic soils had higher TOC, available and residual P, and moderately labile and moderately resistant P, whereas rhyodacitic soils showed higher labile P. The high levels of moderately labile and moderately resistant P fractions in basaltic soil were attributed to its high TOC, available P, and residual P contents. Parent material was found to influence organic P fractions in vineyard soils.

Abstract The basins of Campos and Santos, the most important offshore oil reserves in Brazil, hold potential for being the largest offshore oil exploration fields in the next decades, mainly due to the oil located in the pre-salt layer. This region presents real conditions for the occurrence of intense atmospheric events added to the high velocity of the meanders of the Brazilian current. However, the increasing risk of accidents and damage in the region has been the subject of concern and discussion. The risks in the basins of Campos (2011) and Santos (2012) may not exhibit the the same potential for disastrous events as do those in the oil fields of Alaska and of the Gulf of Mexico, but accidents in these areas are not unlikely, as already evidenced by previous accidents under similar operating conditions (e.g. Chevron Platform accident in Campos Basin, RJ, Brazil, 2011). This paper highlights discussion of the multidisciplinary and substantial environmental features in oil exploration fields along the Brazilian coast based on Semi-Systematic Review methodology. The aspects evaluated cover not only geological traits, oceanic and meteorological circulation, but also current oil production, the most significant oil spill accidents recorded up to 2019 and the discussion about some current levels of seawater contamination.

Abstract This study employed multivariate analysis techniques to identify and evaluate the chemical variables responsible for the contamination of the urban area of ​​Boquira, Bahia, due to the abandonment of the tailings basin of Pb-Zn mining, in order to assist in the environmental management of the area. Factor analysis was performed on main and grouping components. The factor analysis allowed grouping the variables into two main factors for street sediment samples, adding up to 72% of the total accumulated variance, and three factors for house dust samples, which explained 77% of the total variance. The variables have a strong correlation with the composition of the tailings basin. Cluster analysis classified the samples according to the concentration of metals in the area, where the influence of the tailings basin and the natural background of the region's rocks in the contamination distribution can be identified.

Abstract Coffee irrigation has increased in the main Brazilian coffee regions. However, in recent years, with climate change, years with water deficits greater than 150 mm have been observed, affecting the vegetative and productive development of the crop and also the replenishment of surface and underground springs. One practice that increases soil water retention capacity is organic fertilization. This work evaluated different combinations of irrigation and organic fertilization on the yield and quality of coffee produced in the Minas Gerais cerrado region. The treatments were: T1: total irrigation; T2: no irrigation; T3: total irrigation + organic fertilization (chicken manure, 10 ton ha-1); T4: no irrigation + organic fertilization (chicken manure, 10 ton ha-1); T5: 50% irrigation + organic fertilization (chicken manure, 10 ton ha-1). After 7 harvests, it was concluded that the treatment that combined organic fertilization with application of half of the necessary irrigation presented the best yield, superior to the treatment with total irrigation and exclusively mineral nutrition.

Abstract The complexity of evaluating the quality of an aquatic environment with its numerous variables has resulted in several quality indexes to synthesize all information in a single value. However, most of these indexes are based on few environmental variables, losing information from other relevant variables. This article presents a new model capable of representing the quality level of a tropical oligo-mesotrophic reservoir on a numerical scale, considering the subjectivity implicit in the concept of quality, and involving several physical, chemical and biological variables. The proposed model, called "Fuzzy Indices for Water Quality Assessment and Biotics" (FUZZY-WBQAI), is based on fuzzy inference systems, providing a way to deal with the uncertainty between the quality categories. A computational tool was developed, which automatically assesses the quality of water, considering different methodologies that depend on the stratification conditions and the longitudinal zone of the reservoir. The model calculates two indices: one for water quality and one biotic that uses metrics from the fish assembly. The model was effective in revealing the decrease in water quality in summer months with higher temperature and precipitation. The effect of the mixture of the stratified reservoir in winter in decreasing the water quality in an area of ​​fish cultivation was highlighted. The biotic index was sensitive to spatial changes in the environmental quality of the reservoir. The results were considered satisfactory, in agreement with the specialized knowledge, and can provide a rapid diagnosis of water conditions in oligo-mesotrophic reservoirs in the tropics.

Abstract Intensity-duration-frequency (IDF) equations have important applications in several engineering areas such as urban drainage designs, hydrological modeling, and soil conservation projects. This study analyzes the annual maximum series and fits IDF equations for 44 rainfall stations in Alagoas State, Brazil. We adjusted parameters of the Gumbel distribution (GD) and the Generalized Extreme Value (GEV) distribution. The fitting of the observed data to the probability distributions, as well as the selection of the best distribution, were based on the Kolmogorov-Smirnov and Anderson-Darling tests at a 5% significance level. The GEV distribution with parameters obtained by the L-moments method was considered the best in 73% of rainfall stations. The estimated IDF equations showed a good fit, with determination coefficients above 0.991. The maximum rainfall intensities have spatial variation following the climatic zones of the state. The fitted equations allow estimating rainfall intensities from 5 minutes to 24 hours with a return period of 2 to 100 years, and standard error of less than 6.83 mm h-1.

Abstract Jean laundering generates significant effluent flows with a high organic load, color, and other pollutants, making it difficult to adjust effluent releases within legal limits. Slow Sand Filters (SSF) with downflow were tested for seven days (bench scale), to propose an after-treatment of effluents from an Effluent Treatment Plant of a jean laundry. The research evaluated the removal of the following parameters: color, turbidity, chemical and biochemical oxygen demand, conductivity, ammonia, total phosphorus and salinity of the textile effluent. The experimental apparatus had four SSF: the first filter was fed with distilled water, while the other three filters (triplicates) were fed with effluent. The filters had, on average, the following removal efficiencies: 91% for ammonia, 61.24% color, 89.43% turbidity, and 83.54% for phosphorus. Regarding the removal of organic matter, 98.11% for BOD and 81.17% for COD, demonstrating that SSFs were efficient in removing particulate, dissolved materials and organic matter.

Abstract Ozone is an oxidizing agent with a potential for removing complex molecules, including those of difficult microbiological decomposition, such as the molecules found in landfill leachates. This effluent presents high organic content, including recalcitrant molecules. Therefore, this study evaluated the efficiency of ozonation in the treatment of raw leachate at the Primavera landfill, located in Mato Grosso, Brazil. The experiments were carried out using the batch system. The leachate pH value was set at 7 and 10, and the contact times between the gas and the leachate were 20, 40, 60, 80, and 100 minutes. Throughout the study, we analyzed color, turbidity, pH value, chemical oxygen demand (COD), and ultraviolet absorbance at 254 nm (UV abs) of the leachate, both before and after ozonation. Results show that ozonation presented high removal of color, COD and UV abs when pH was 7. In contrast, turbidity removal was higher when the pH value was 10. Regarding contact time, we observed a high removal of color (between 80% and 90%) and UV abs (between 60% and 70%) at 40 minutes, depending on the pH value. Removal was also high for turbidity (approximately 75%) starting at 20 minutes with the pH value at 10, and at 70 minutes with pH at 7. The removal relation within all analyzed parameters (due to ozone consumption) decreased throughout the reaction time. Thus, we concluded that ozonation as a pre-treatment of leachate is indeed satisfactory because of its great capacity for organic material removal.

Abstract Pleurotus fungi are basidiomycetes that stand out in the degradation of recalcitrant organic compounds such as lignin derivatives and phenolic compounds. The aim of this study was to make a comparative evaluation of the capacity of the Pleurotus ostreatus POS 560 and Pleurotus floridae PSP1 fungi in the degradation of 2,4 and 2,6-dinitrotoluene (DNTs) in effluent from an explosive factory. The characterization of the effluent indicated 318 mg L-1 of DNTs, 246 mg L-1 of COD and toxicity factor for Daphnia magna corresponding to 8. The conduct of a multivariate study estimated the influence of the variables pH (5.0 and 6.0), co-substrate concentration (10 and 20 g L-1 of glucose) and species of the fungus Pleurotus (ostreatus and floridae) on the degradation of DNTs, indicating that the variables Fungus and [Glucose] were significant (p <0.05) presenting effects in the order of + 4.45 ± 0.26 and -1.14 ± 0.26, respectively. The reproduction of the best efficiency conditions (P. floridae; pH 6.0 and 10 g L-1 of glucose) in agitated flasks (100 rpm, 26oC) was able to carry out, within 14 days of treatment, the removal of organic matter and toxicity factor in levels on the order of 55 and 50%, respectively, in addition to the complete degradation of DNTs which occurred in the first 120 hours of treatment. In this period, the maximum activity of the peroxidase and Mn-peroxidase enzymes was also characterized, suggesting high potential of the bioprocess under study for remediation of effluents contaminated with nitroaromatic compounds.

Abstract Water contamination comes from many different sources, including, among others, factories, sewage treatment plants, mining activities (heavy metals), food-processing waste, agriculture runoff, animal waste, disposal of personal care products, and household chemicals. Therefore, the reuse of wastewater has become a fundamental strategy for sustainable water management and maintaining environmental quality. In this sense, this research presents a simple and economic alternative to solving the problems caused by greywater, resulting from laundry activities. This paper evaluates a mixed system for the treatment of greywater. The mixed system has physical filters that are composed of river stone, concrete, river sand, and coal. A bioremediation technique is also evaluated, involving two types of aquatic plants, watercress (Nasturtium officinale L.) and duckweed (Lemma minor L.). This study showed significant differences in pH reduction, from 9.56 to 7.50, total suspended solids (TSS), from 1742.00 mg/L to 298.50 mg/L, phosphates, from 1.12 mg/L PO4 3¯ to 0.31 mg/L PO4 3- , and chemical oxygen demand (COD), from 472.38 mg/L to 8.52 mg/L. Thus, the results indicate that this system is efficient for the reuse of grey water for irrigation uses. Moreover, each parameter, with the exception of dissolved oxygen and total suspended solids (TSS), meets the maximum limits set by the Environmental Quality Standards for Category 3: irrigation water for vegetables and animal beverages and the FAO irrigation water standards.

Abstract This study evaluated the physiological quality and quantified the efficiency of polymer in reducing the loss of phytosanitary products by leaching from soybean seeds of different diameters and in different treatments. Two lots of seed and two types of treatments were tested: polymers associated with seed treatment, and polymer application in layers after the seed treatment. For that, the following treatments were analyzed: Control= no seed treatment; Treat+pol= seed treatment + polymers in the mix; Treat/pol= seed treatment + polymers applied in layers; Treat= seed treatment. To evaluate seed treatment retention by the polymers, extraction equipment was employed and leaching of the active ingredient thiamethoxam was quantified. Evaluation of physical quality was conducted with tests of germination rate, first count, emergence rate, accelerated aging, seedling length, seedling dry mass and moisture content. Polymer application associated with seed treatment was efficient in reducing losses by leaching, reducing product loss by 20%. No significant differences in retention and physiological quality were found when different methods for polymer application were compared. Bigger seeds presented greater vigor, but the germination rate was unaffected.

Abstract The surveillance of the concentration of fluoride in the public water supply aims to ensure the balance between the benefits (carie prevention) and risk (dental fluorosis) of water fluoridation programs. The aim of this study was to check the accuracy of two analytical methods for monitoring the concentration of fluoride in the public water supply of a Brazilian city. The STROBE checklist was used to aid the conduction of this study and report the results. It was an analytical, observational, and prospective study using the water supply of Uberlândia, MG, Brazil. We collected 126 water samples at 21 sites for six consecutive months and analyzed them using the fluoride ion selective electrode (F-ISE) method and colorimetry with SPADNS. The statistical analysis was performed descriptively and then the ANOVA and Student t-test for paired samples were applied. The results showed that the F-ISE method had a lower coefficient of variation (12.3%) than the SPADNS method (57.4%). There was no significant variation of the fluoride concentration in the water through the supply network evaluated either by F-ISE as SPADNS. We concluded that the electrometric method should be the first choice for use by laboratories that monitor fluoride concentration in the public supply water.

Abstract The use of natural coagulants is a promising alternative to replace or assist chemical coagulants due to its numerous advantages. This paper evaluates the effectiveness of a natural coagulant in water treatment. The coagulant was extracted from the Zygia cauliflora (Willd.) Killip seed in saline solutions and defatted using 95% ethanol. The tests were conducted using different concentrations of the coagulant (0.1, 0.5, 1.0, 2.0, 3.0, and 4.0 g L-1) and of NaCl (0.0 M, 1.0 M, and 5.0 M). The results showed that the use of 2 g L-1 of coagulant and 1.0 M of the salt achieved an effectiveness of 20% and 70%, respectively, of color and turbidity removal. The analysis showed an effectiveness of 70% and 30%, respectively, when removing the UV254 compound and DOM (dissolved organic matter). The mechanism for turbidity removal by the coagulants prepared with aqueous solution and with saline solution at 1.0 M of NaCl is supposed to be adsorption and charge neutralization, respectively, following the Freundlich and Langmuir models. However, the coagulant prepared with saline solution at 5.0 M of NaCl tends to form a netlike structure followed by turbidity removal through a sweep coagulation mechanism. Future papers should therefore focus on the use of Zygia cauliflora (Willd.) Killip as an alternative for replacement or use as an auxiliary chemical coagulant.

Abstract A full-scale sewage treatment plant was investigated to assess the performance of the disinfection stage. Sodium hypochlorite was used as a disinfectant agent and the process efficiency was evaluated by E.coli removal. The research took place over a period of two years in order to evaluate the effect of retention time (t) and residual chlorine (Cr) under different seasonal conditions. The effectiveness of E.coli removal with sodium hypochlorite proved to be strictly dependent on the factor CR t (product of residual chlorine with the contact time). The regression line of the experimental points was, on the whole, well comparable with the model proposed by Collins, especially in the field of CRt lower than 30 mg L-1 min.